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  • Title: Pd(II)-Catalyzed arylation of unactivated methylene C(sp3)-H bonds with aryl halides using a removable auxiliary.
    Author: Zhang Q, Yin XS, Zhao S, Fang SL, Shi BF.
    Journal: Chem Commun (Camb); 2014 Aug 07; 50(61):8353-5. PubMed ID: 24943091.
    Abstract:
    A Pd(II)-catalyzed arylation of methylene C(sp(3))-H bonds in aliphatic amides directed by our newly developed PIP directing group with aryl iodides/bromides has been achieved. Arylation occurs efficiently with a broad range of aryl halides and amides.
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