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  • Title: Scalable, transition-metal-free direct oxime O-arylation: rapid access to O-arylhydroxylamines and substituted benzo[b]furans.
    Author: Gao H, Xu QL, Keene C, Kürti L.
    Journal: Chemistry; 2014 Jul 14; 20(29):8883-7. PubMed ID: 24953184.
    Abstract:
    O-aryloximes, generated from readily available and inexpensive oximes through transition-metal-free O-arylation, can either be hydrolyzed to O-arylhydroxylamines or conveniently converted to structurally diverse benzo[b]furans through an environmentally benign, one-pot [3,3]-sigmatropic rearrangement/cyclization sequence.
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