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Title: General synthesis of multi-shelled mixed metal oxide hollow spheres with superior lithium storage properties. Author: Zhang G, Lou XW. Journal: Angew Chem Int Ed Engl; 2014 Aug 18; 53(34):9041-4. PubMed ID: 24962932. Abstract: Complex hollow structures of transition metal oxides, especially mixed metal oxides, could be promising for different applications such as lithium ion batteries. However, it remains a great challenge to fabricate well-defined hollow spheres with multiple shells for mixed transition metal oxides. Herein, we have developed a new "penetration-solidification-annealing" strategy which can realize the synthesis of various mixed metal oxide multi-shelled hollow spheres. Importantly, it is found that multi-shelled hollow spheres possess impressive lithium storage properties with both high specific capacity and excellent cycling stability. Specifically, the carbon-coated CoMn2O4 triple-shelled hollow spheres exhibit a specific capacity of 726.7 mA h g(-1) and a nearly 100 % capacity retention after 200 cycles. The present general strategy could represent a milestone in design and synthesis of mixed metal oxide complex hollow spheres and their promising uses in different areas.[Abstract] [Full Text] [Related] [New Search]