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  • Title: Rapid access to spirocyclized indolenines via palladium-catalyzed cascade reactions of tryptamine derivatives and propargyl carbonate.
    Author: Montgomery TD, Nibbs AE, Zhu Y, Rawal VH.
    Journal: Org Lett; 2014 Jul 03; 16(13):3480-3. PubMed ID: 24964382.
    Abstract:
    We report the intermolecular palladium-catalyzed reaction of tert-butyl propargyl carbonate with tryptamine derivatives or other indole-containing bis-nucleophiles. The reaction proceeds under mild conditions and with low catalyst loadings to afford novel spiroindolenine products in good to high yields.
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