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  • Title: Synthesis of tertiary propargylamines via a rationally designed multicomponent reaction of primary amines, formaldehyde, arylboronic acids and alkynes.
    Author: Wang J, Shen Q, Li P, Peng Y, Song G.
    Journal: Org Biomol Chem; 2014 Aug 14; 12(30):5597-600. PubMed ID: 24969221.
    Abstract:
    A novel approach for the synthesis of tertiary propargylamines is achieved through a Cu(OAc)2-catalyzed multicomponent reaction of primary amines, formaldehyde, arylboronic acids and alkynes, where a combination of PBM and A(3)-coupling reactions is involved in this new multicomponent reaction.
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