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  • Title: Enantioselective hydrogenation of α,β-disubstituted nitroalkenes.
    Author: Li S, Huang K, Zhang X.
    Journal: Chem Commun (Camb); 2014 Aug 18; 50(64):8878-81. PubMed ID: 24970566.
    Abstract:
    The first highly chemo- and enantioselective hydrogenation of α,β-disubstituted nitroalkenes was accomplished with rhodium/JosiPhos-J2 as a catalyst, with the yield and enantioselectivity of up to 95% and 94%, respectively. The α-chiral nitroalkanes will provide an entry to valuable chiral amphetamines which are otherwise not so easily accessed.
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