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  • Title: Stereoselective synthesis of cis-2-fluorocyclopropanecarboxylic acid.
    Author: Shibue T, Fukuda Y.
    Journal: J Org Chem; 2014 Aug 01; 79(15):7226-31. PubMed ID: 25010939.
    Abstract:
    A rhodium-catalyzed cyclopropanation of 1-fluoro-1-(phenylsulfonyl)ethylene and diazo esters is described as an effective method for the stereoselective synthesis of cis-2-fluorocyclopropanecarboxylic acid. This process provides an example of the cyclopropanation of electron-deficient olefin and diazoacetates.
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