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  • Title: Palladium-catalyzed cross-coupling reaction of diazo compounds and vinyl boronic acids: an approach to 1,3-diene compounds.
    Author: Xia Y, Xia Y, Liu Z, Zhang Y, Wang J.
    Journal: J Org Chem; 2014 Aug 15; 79(16):7711-7. PubMed ID: 25019414.
    Abstract:
    A palladium-catalyzed oxidative cross-coupling of vinyl boronic acids and cyclic α-diazocarbonyl compounds has been reported. The reaction constitutes an efficient method for the synthesis of 1,3-diene compounds bearing a ring structure. Mechanistically, the reaction involves migratory insertion of palladium carbene as the key step.
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