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  • Title: Catalytic enantioselective C-H functionalization of alcohols by redox-triggered carbonyl addition: borrowing hydrogen, returning carbon.
    Author: Ketcham JM, Shin I, Montgomery TP, Krische MJ.
    Journal: Angew Chem Int Ed Engl; 2014 Aug 25; 53(35):9142-50. PubMed ID: 25056771.
    Abstract:
    The use of alcohols and unsaturated reactants for the redox-triggered generation of nucleophile-electrophile pairs represents a broad, new approach to carbonyl addition chemistry. Discrete redox manipulations that are often required for the generation of carbonyl electrophiles and premetalated carbon-centered nucleophiles are thus avoided. Based on this concept, a broad, new family of enantioselective C-C coupling reactions that are catalyzed by iridium or ruthenium complexes have been developed, which are summarized in this Minireview.
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