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  • Title: Synthesis of silyl monoperoxyketals by regioselective cobalt-catalyzed peroxidation of silyl enol ethers: application to the synthesis of 1,2-dioxolanes.
    Author: Hurlocker B, Miner MR, Woerpel KA.
    Journal: Org Lett; 2014 Aug 15; 16(16):4280-3. PubMed ID: 25084342.
    Abstract:
    The cobalt-catalyzed peroxidation of silyl enol ethers with molecular oxygen and triethylsilane provided silyl monoperoxyketals in 54%-96% yield. These compounds serve as precursors to peroxycarbenium ions, which undergo annulations to provide 1,2-dioxolanes.
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