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  • Title: Biogenetically inspired total syntheses of Lycopodium alkaloids, (+)-flabellidine and (-)-lycodine.
    Author: Azuma M, Yoshikawa T, Kogure N, Kitajima M, Takayama H.
    Journal: J Am Chem Soc; 2014 Aug 20; 136(33):11618-21. PubMed ID: 25103992.
    Abstract:
    The first asymmetric total synthesis of (+)-flabellidine (2) and the shortest total synthesis of (-)-lycodine (3) were accomplished by a strategy featuring the one-pot construction of a tetracyclic lycodine skeleton from a linear precursor, which was inspired by the biosynthetic consideration of Lycopodium alkaloids.
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