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  • Title: Novel pathways to 2,5-dimethylfuran via biomass-derived 5-(chloromethyl)furfural.
    Author: Dutta S, Mascal M.
    Journal: ChemSusChem; 2014 Nov; 7(11):3028-30. PubMed ID: 25196591.
    Abstract:
    2,5-Dimethylfuran (DMF) is one of the most actively pursued biomass-derived chemicals due to the fact that it can serve both as a biofuel and an intermediate for drop-in terephthalate polymers. DMF can be accessed via catalytic hydrogenation of 5-(hydroxymethyl)furfural (HMF), but the difficult accessibility of HMF from cellulosic biomass is a major impediment to the commercial development of such a process. Alternatively, 5-(chloromethyl)furfural (CMF) is freely accessible in high yield directly from raw biomass and is shown here to be efficiently reduced to DMF under mild conditions via simple derivatives (aldimine, acetal).
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