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  • Title: The isomerization of allylrhodium intermediates in the rhodium-catalyzed nucleophilic allylation of cyclic imines.
    Author: Hepburn HB, Lam HW.
    Journal: Angew Chem Int Ed Engl; 2014 Oct 20; 53(43):11605-10. PubMed ID: 25205604.
    Abstract:
    Allylrhodium species generated from potassium allyltrifluoroborates can undergo isomerization by 1,4-rhodium(I) migration to give more complex isomers, which then react with cyclic imines to provide products with up to three new stereochemical elements. High enantioselectivities are obtained using chiral diene-rhodium complexes.
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