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  • Title: A biferrocenium salt containing paramagnetic tetracyanoquinodimethane hexamers: charge disproportionation via donor-acceptor interactions.
    Author: Mochida T, Funasako Y, Takahashi K, Inokuchi M, Sakurai T, Ikeda S, Ohta H, Mori H, Uruichi M.
    Journal: Chem Commun (Camb); 2014 Nov 11; 50(87):13370-2. PubMed ID: 25233286.
    Abstract:
    [Dineopentyl-biferrocene]2[Cl1TCNQ]7, which has an unprecedented high donor-acceptor ratio of 2 : 7, contains a linear paramagnetic hexamer of Cl1TCNQ. Both the donor and acceptor molecules exhibit charge disproportionation in the crystal through mutual electrostatic interactions.
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