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  • Title: Catalytic methylation of aromatic amines with formic acid as the unique carbon and hydrogen source.
    Author: Savourey S, Lefèvre G, Berthet JC, Cantat T.
    Journal: Chem Commun (Camb); 2014 Nov 21; 50(90):14033-6. PubMed ID: 25268489.
    Abstract:
    A novel methodology is presented for the direct methylation of amines, using formic acid as a unique source of carbon and hydrogen. Based on ruthenium(II) catalysts, the formation of the N-CH3 group proceeds via an efficient formylation/transfer hydrogenation pathway.
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