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  • Title: Rhodium-catalyzed ortho-cyanation of symmetrical azobenzenes with N-cyano-N-phenyl-p-toluenesulfonamide.
    Author: Han J, Pan C, Jia X, Zhu C.
    Journal: Org Biomol Chem; 2014 Nov 21; 12(43):8603-6. PubMed ID: 25268970.
    Abstract:
    A rhodium-catalyzed ortho-cyanation of symmetrical azobenzenes is described employing N-cyano-N-phenyl-p-toluenesulfonamide as an environmentally friendly cyanide source. The present protocol allows the synthesis of various benzonitrile derivatives in moderate to good yields and tolerates many useful functional groups.
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