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  • Title: Understanding the adsorption mechanism of noble gases Kr and Xe in CPO-27-Ni, CPO-27-Mg, and ZIF-8.
    Author: Magdysyuk OV, Adams F, Liermann HP, Spanopoulos I, Trikalitis PN, Hirscher M, Morris RE, Duncan MJ, McCormick LJ, Dinnebier RE.
    Journal: Phys Chem Chem Phys; 2014 Nov 21; 16(43):23908-14. PubMed ID: 25277596.
    Abstract:
    An experimental study of Xe and Kr adsorption in metal-organic frameworks CPO-27-Ni, CPO-27-Mg, and ZIF-8 was carried out. In situ synchrotron X-ray powder diffraction experiments allowed precise determination of the adsorption sites and sequence of their filling with increasing of gas pressure at different temperatures. Structural investigations were used for interpretation of gas adsorption measurements.
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