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  • Title: The first route to highly stable crystalline microporous zirconium phosphonate metal-organic frameworks.
    Author: Taddei M, Costantino F, Marmottini F, Comotti A, Sozzani P, Vivani R.
    Journal: Chem Commun (Camb); 2014 Dec 07; 50(94):14831-4. PubMed ID: 25325082.
    Abstract:
    The first crystalline microporous zirconium phosphonate metal-organic framework (UPG-1) was synthesized using the novel tritopic ligand 2,4,6-tris(4-(phosphonomethyl)phenyl)-1,3,5-triazine. Its crystal structure was solved ab initio from laboratory powder X-ray diffraction data. UPG-1 displays remarkable thermal stability and hydrolysis resistance and has a good absorption affinity towards n-butane and CO2.
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