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  • Title: Post-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination.
    Author: So MC, Beyzavi MH, Sawhney R, Shekhah O, Eddaoudi M, Al-Juaid SS, Hupp JT, Farha OK.
    Journal: Chem Commun (Camb); 2015 Jan 04; 51(1):85-8. PubMed ID: 25325833.
    Abstract:
    Herein, we demonstrate the robustness of layer-by-layer (LbL)-assembled, pillared-paddlewheel-type MOF films toward conversion to new or modified MOFs via solvent-assisted linker exchange (SALE) and post-assembly linker metalation. Further, we show that LbL synthesis can afford MOFs that have proven inaccessible through other de novo strategies.
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