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  • Title: Heavier alkaline earth catalyzed ene-yne cyclizations: atom-efficient access to tetrahydroisoquinoline frameworks.
    Author: Reid S, Barrett AG, Hill MS, Procopiou PA.
    Journal: Org Lett; 2014 Nov 21; 16(22):6016-9. PubMed ID: 25383983.
    Abstract:
    Tetrahydroisoquinoline frameworks may be accessed with 100% atom efficiency through the alkaline earth catalyzed addition of primary amines to ene-yne substrates through a sequence of intermolecular alkene and intramolecular alkyne hydroamination steps.
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