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  • Title: High-performance asymmetric supercapacitors based on multilayer MnO2 /graphene oxide nanoflakes and hierarchical porous carbon with enhanced cycling stability.
    Author: Zhao Y, Ran W, He J, Huang Y, Liu Z, Liu W, Tang Y, Zhang L, Gao D, Gao F.
    Journal: Small; 2015 Mar 18; 11(11):1310-9. PubMed ID: 25384679.
    Abstract:
    In this work, MnO(2)/GO (graphene oxide) composites with novel multilayer nanoflake structure, and a carbon material derived from Artemia cyst shell with genetic 3D hierarchical porous structure (HPC), are prepared. An asymmetric supercapacitor has been fabricated using MnO(2)/GO as positive electrode and HPC as negative electrode material. Because of their unique structures, both MnO(2)/GO composites and HPC exhibit excellent electrochemical performances. The optimized asymmetric supercapacitor could be cycled reversibly in the high voltage range of 0-2 V in aqueous electrolyte, which exhibits maximum energy density of 46.7 Wh kg(-1) at a power density of 100 W kg(-1) and remains 18.9 Wh kg(-1) at 2000 W kg(-1). Additionally, such device also shows superior long cycle life along with ∼100% capacitance retention after 1000 cycles and ∼93% after 4000 cycles.
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