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  • Title: Indium(III) chloride catalyzed highly diastereoselective domino synthesis of indenodithiepines and indenodithiocines.
    Author: Muthusamy S, Sivaguru M, Suresh E.
    Journal: Chem Commun (Camb); 2015 Jan 14; 51(4):707-10. PubMed ID: 25418338.
    Abstract:
    An atom-economical diastereoselective synthesis of indenodithiepines and indenodithiocines has been developed via a domino reaction of propargylic alcohols and dithioacetals in the presence of InCl3 as a catalyst. A range of functionalized dithiepines and dithiocines, fused to the indene ring, were obtained in good to excellent yields under mild conditions.
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