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Title: Novel indole based dual responsive "turn-on" chemosensor for fluoride ion detection. Author: Jeyanthi D, Iniya M, Krishnaveni K, Chellappa D. Journal: Spectrochim Acta A Mol Biomol Spectrosc; 2015 Feb 05; 136 Pt C():1269-74. PubMed ID: 25456669. Abstract: An efficient new dual channel chemosensor 2,3-bis((E)-(1H-indole-3-yl)methyleneamino)maleonitrile (DN) which exhibits selective sensing of F(-) ions in DMSO, was synthesized by a facile one step condensation reaction of indole-3-carboxaldehyde with diaminomaleonitrile. The probe DN was characterized by elemental analysis, (1)H, (13)C-NMR, ESI-MS and IR spectral techniques. Upon addition of F(-), DN induces remarkable changes in both absorption and fluorescence spectra on the basis of charge transfer mechanism. The receptor DN serves for highly selective, sensitive detection of F(-) without the interference of other relevant anions. The Job's plot analysis indicates the binding stoichiometry to be 1:1 (host/guest).[Abstract] [Full Text] [Related] [New Search]