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  • Title: A colorimetric and fluorescent cyanide chemosensor based on dicyanovinyl derivatives: utilization of the mechanism of intramolecular charge transfer blocking.
    Author: Li Q, Cai Y, Yao H, Lin Q, Zhu YR, Li H, Zhang YM, Wei TB.
    Journal: Spectrochim Acta A Mol Biomol Spectrosc; 2015 Feb 05; 136 Pt B():1047-51. PubMed ID: 25459631.
    Abstract:
    Chemosensor (CS1) was designed and synthesized by simple green chemistry procedure. CS1 exhibited both colorimetric and fluorescence turn-off responses for cyanide (CN(-)) ion in aqueous solution. The probe showed an immediate visible color changes from yellow to colorless and green fluorescence disappearance when CN(-) was added. The mechanism of chemosensor reaction with CN(-) was studied using (1)HH NMR and (13)C NMR spectroscopies and mass spectrometry. Moreover, test strips based on the sensor were fabricated, which served as convenient and efficient CN(-) test kits.
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