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  • Title: Diterpene alkaloids with an aza-ent-kaurane skeleton from Isodon rubescens.
    Author: Liu X, Yang J, Wang WG, Li Y, Wu JZ, Pu JX, Sun HD.
    Journal: J Nat Prod; 2015 Feb 27; 78(2):196-201. PubMed ID: 25590529.
    Abstract:
    Two compounds belonging to a new group of diterpene alkaloids, kaurines A and B (1 and 2), and an alkaloid bearing a succinimide moiety (3) were obtained from Isodon rubescens. Their structures and absolute configurations were determined by spectroscopy and quantum-chemical computational (13)C NMR and ECD data analysis. These alkaloids differ from known diterpene alkaloids and diterpenoids and are presumably biosynthesized from ent-kaurane diterpenoids.
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