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  • Title: Bicyclobutonium ions in biosynthesis--interconversion of cyclopropyl-containing sterols from orchids.
    Author: Hong YJ, Giner JL, Tantillo DJ.
    Journal: J Am Chem Soc; 2015 Feb 11; 137(5):2085-8. PubMed ID: 25607948.
    Abstract:
    Theoretical investigation of cyclopropane-to-cyclopropane rearrangements of sterols indicates a role for highly delocalized bicyclobutonium ions in biosynthesis.
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