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  • Title: pH- and sugar-induced shape memory hydrogel based on reversible phenylboronic acid-diol ester bonds.
    Author: Meng H, Zheng J, Wen X, Cai Z, Zhang J, Chen T.
    Journal: Macromol Rapid Commun; 2015 Mar; 36(6):533-7. PubMed ID: 25630431.
    Abstract:
    A simple strategy is provided to construct a novel pH- and sugar-induced shape memory hydrogel based on dynamic phenylboronic acid (PBA)-diol interactions formed by PBA-modified sodium alginate (Alg-PBA) and poly(vinyl alcohol) (PVA). The dynamic PBA-diol ester bonds serve as temporary cross-links and stabilize the deformed shape of the hydrogel. The disassociation of the PBA-diol ester bonds is explored in acidic conditions and aqueous solutions of glucose and fructose, which endow the hydrogel with shape memory performances.
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