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  • Title: Synthesis of the tetracyclic skeleton of the Lycopodium alkaloid lycopladine H via a pivotal double hydroformylation/intramolecular reductive amination sequence.
    Author: Chauhan PS, Sacher JR, Weinreb SM.
    Journal: Org Lett; 2015 Feb 20; 17(4):806-8. PubMed ID: 25658603.
    Abstract:
    A synthesis of the complete tetracyclic framework of the structurally unique Lycopodium alkaloid lycopladine H has been accomplished using a strategy involving a double alkene hydroformylation/intramolecular reductive amination to form the azocane and spiro-piperidine moieties of the natural product.
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