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  • Title: Room temperature C-P bond formation enabled by merging nickel catalysis and visible-light-induced photoredox catalysis.
    Author: Xuan J, Zeng TT, Chen JR, Lu LQ, Xiao WJ.
    Journal: Chemistry; 2015 Mar 23; 21(13):4962-5. PubMed ID: 25688851.
    Abstract:
    A novel and efficient C-P bond formation reaction of diarylphosphine oxides with aryl iodides was achieved by combining nickel catalysis and visible-light-induced photoredox catalysis. This dual-catalytic reaction showed a broad substrate scope, excellent functional group tolerance, and afforded the corresponding products in good to excellent yields. Compared with the previously reported use of photoredox/nickel dual catalysis in the construction of C-C bonds, the methodology described herein was observed to be the first to allow for C-heteroatom bond formation.
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