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  • Title: Biomimetic synthesis of dendridine A.
    Author: Boyd EM, Sperry J.
    Journal: Org Lett; 2015 Mar 06; 17(5):1344-6. PubMed ID: 25699647.
    Abstract:
    Biomimetic synthesis of the bisindole natural product dendridine A is reported. Although attempts to install the hindered biaryl bond by oxidative phenolic coupling of the 7-hydroxytryptamine 6 gave the undesired ortho-ortho product, a Scholl-type oxidative coupling of the 7-isopropoxytryptamine 9 with molybdenum pentachloride proceeded through the desired para-para pathway, installing the entire carbon framework of dendridine A.
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