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  • Title: Gargantulide A, a complex 52-membered macrolactone showing antibacterial activity from Streptomyces sp.
    Author: Rho JR, Subramaniam G, Choi H, Kim EH, Ng SP, Yoganathan K, Ng S, Buss AD, Butler MS, Gerwick WH.
    Journal: Org Lett; 2015 Mar 20; 17(6):1377-80. PubMed ID: 25723256.
    Abstract:
    Gargantulide A (1), an extremely complex 52-membered macrolactone, was isolated from Streptomyces sp. A42983 and displayed moderate activity against MRSA. The planar structure of 1 was determined using 2D NMR, and its stereochemistry was partially established on the basis of NOESY correlations, J-based configuration analysis, and Kishi's universal NMR database.
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