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  • Title: Pd-catalyzed enantioselective intramolecular α-arylation of α-substituted cyclic ketones: facile synthesis of functionalized chiral spirobicycles.
    Author: Fan L, Takizawa S, Takeuchi Y, Takenaka K, Sasai H.
    Journal: Org Biomol Chem; 2015 May 07; 13(17):4837-40. PubMed ID: 25806855.
    Abstract:
    Catalytic synthesis of chiral spirocyclic ketones was accomplished via the Pd-catalyzed intramolecular α-arylation of α-substituted cyclic ketones. The obtained spirocyclic ketone could be converted into a bifunctional organocatalyst.
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