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  • Title: Development and Application of α-Heteroatom Ketones in Asymmetric Michael Reaction with β-trans-Nitroalkenes.
    Author: Yang D, Li D, Wang L, Zhao D, Wang R.
    Journal: J Org Chem; 2015 May 01; 80(9):4336-48. PubMed ID: 25853329.
    Abstract:
    The successful design and application of a new type of N-phenyl-imidazole-modified α-heteroatom ketones in asymmetric anti-selective Michael reactions with β-trans-nitroalkenes is reported. High yields and enantioselectivities could be obtained, and the corresponding conjugate adducts could be further transformed into related chiral esters and cyclopropane derivatives with excellent enantioselectivities.
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