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  • Title: Total Synthesis of Paecilomycin B.
    Author: Ohba K, Nakata M.
    Journal: Org Lett; 2015 Jun 19; 17(12):2890-3. PubMed ID: 25937148.
    Abstract:
    Starting from the glucose-derived δ-lactone and the functionalized aryl bromide, the first total synthesis of naturally occurring paecilomycin B was achieved via functionalized aryl-β-C-glycoside synthesis using 2,4,6-triisopropylphenyllithium under Barbier-type reaction conditions and ring-closing metathesis as the key steps.
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