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Title: Stochastic approach to equilibrium and nonequilibrium thermodynamics. Author: Tomé T, de Oliveira MJ. Journal: Phys Rev E Stat Nonlin Soft Matter Phys; 2015 Apr; 91(4):042140. PubMed ID: 25974471. Abstract: We develop the stochastic approach to thermodynamics based on stochastic dynamics, which can be discrete (master equation) and continuous (Fokker-Planck equation), and on two assumptions concerning entropy. The first is the definition of entropy itself and the second the definition of entropy production rate, which is non-negative and vanishes in thermodynamic equilibrium. Based on these assumptions, we study interacting systems with many degrees of freedom in equilibrium or out of thermodynamic equilibrium and how the macroscopic laws are derived from the stochastic dynamics. These studies include the quasiequilibrium processes; the convexity of the equilibrium surface; the monotonic time behavior of thermodynamic potentials, including entropy; the bilinear form of the entropy production rate; the Onsager coefficients and reciprocal relations; and the nonequilibrium steady states of chemical reactions.[Abstract] [Full Text] [Related] [New Search]