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Title: Copper(I)-catalyzed carbon-halogen bond-selective boryl substitution of alkyl halides bearing terminal alkene moieties. Author: Iwamoto H, Kubota K, Yamamoto E, Ito H. Journal: Chem Commun (Camb); 2015 Jun 14; 51(47):9655-8. PubMed ID: 25977952. Abstract: The selective boryl substitution of alkyl halides bearing terminal C[double bond, length as m-dash]C double bonds has been achieved using a copper(i)/tricyclohexylphosphine or copper(i)/o-diphenylphosphinophenol catalyst. This reaction represents a useful complementary approach to conventional procedures for the hydroboration of C[double bond, length as m-dash]C double bonds or the borylative cyclization of alkyl halides bearing terminal alkenes.[Abstract] [Full Text] [Related] [New Search]