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  • Title: Alkyl-aryl ketone synthesis via nickel-catalyzed reductive coupling of alkyl halides with aryl acids and anhydrides.
    Author: Jia X, Zhang X, Qian Q, Gong H.
    Journal: Chem Commun (Camb); 2015 Jun 28; 51(51):10302-5. PubMed ID: 26023832.
    Abstract:
    The present work disclosed a considerably improved method for the construction of alkyl-aryl ketones by the direct coupling of unactivated alkyl bromides with 1.5 equiv. of acids. In addition, the synthesis of aroyl C-glycosides was first achieved by the reductive coupling of 1-glycosyl bromides with acid derivatives, which may otherwise require multi-step synthesis.
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