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Title: Gadolinium-Catalyzed Regio- and Enantioselective Aminolysis of Aromatic trans-2,3-Epoxy Sulfonamides. Author: Wang C, Yamamoto H. Journal: Angew Chem Int Ed Engl; 2015 Jul 20; 54(30):8760-3. PubMed ID: 26058560. Abstract: The first enantioselective aminolysis of aromatic trans-2,3-epoxy sulfonamides has been accomplished, which was efficiently catalyzed by a Gd-N,N'-dioxide complex. Under the directing effect of the sulfonamide moiety the ring-opening reaction proceeded selectively at the C-3 position in a highly enantioselective manner furnishing various Ts- and SES-protected 3-amino-3-phenylpropan-2-olamines as products.[Abstract] [Full Text] [Related] [New Search]