These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: Rhodium-Catalyzed Synthesis of Benzosilolometallocenes via the Dehydrogenative Silylation of C(sp(2))-H Bonds.
    Author: Murai M, Matsumoto K, Takeuchi Y, Takai K.
    Journal: Org Lett; 2015 Jun 19; 17(12):3102-5. PubMed ID: 26061112.
    Abstract:
    Use of a rhodium catalyst with electron-rich and bulky chiral diphosphine ligands having C2-symmetry allowed efficient dehydrogenative silylation of the C(sp(2))-H bond of ferrocenes leading to chiral benzosiloloferrocenes. The substrate scope was expanded to hydrogermane and hydrosilanes having a ruthenocene backbone, which resulted in a new approach to benzosilole- and benzogermole-fused metallocenes.
    [Abstract] [Full Text] [Related] [New Search]