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  • Title: Rhodium(III)-catalyzed cyanation of vinylic C-H bonds: N-cyano-N-phenyl-p-toluenesulfonamide as a cyanation reagent.
    Author: Su W, Gong TJ, Xiao B, Fu Y.
    Journal: Chem Commun (Camb); 2015 Jul 28; 51(59):11848-51. PubMed ID: 26108194.
    Abstract:
    Rh(III)-catalyzed direct vinylic C-H cyanation reaction has been developed as a practical method for the synthesis of alkenyl nitriles. N-Cyano-N-phenyl-p-methylbenzenesulfonamide (NCTS), a user-friendly cyanation reagent, was used in the transformation. Both acrylamides and ketoximes can be employed in the new C-H cyanation process.
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