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  • Title: Self-assembly formation of a healable lanthanide luminescent supramolecular metallogel from 2,6-bis(1,2,3-triazol-4-yl)pyridine (btp) ligands.
    Author: McCarney EP, Byrne JP, Twamley B, Martínez-Calvo M, Ryan G, Möbius ME, Gunnlaugsson T.
    Journal: Chem Commun (Camb); 2015 Sep 25; 51(74):14123-6. PubMed ID: 26258184.
    Abstract:
    The synthesis of five new 2,6-bis(1,2,3-triazol-4-yl)pyridine (btp) ligands is described: the self-assembly behaviour of the tri-methyl ester, 1, with Eu(III) showed the formation of a luminescent 1:3 Eu : btp complex, Eu13, which was studied in solution and in the solid state; while the tri-carboxylic acid, 2, formed a hydrogel and its corresponding complex Eu23, gave rise to a strongly red luminescent healable metallogel.
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