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  • Title: Ortho C-H Acylation of Aryl Iodides by Palladium/Norbornene Catalysis.
    Author: Dong Z, Wang J, Ren Z, Dong G.
    Journal: Angew Chem Int Ed Engl; 2015 Oct 19; 54(43):12664-8. PubMed ID: 26333071.
    Abstract:
    Reported herein is a palladium/norbornene-catalyzed ortho-arene acylation of aryl iodides by a Catellani-type C-H functionalization. This transformation is enabled by isopropyl carbonate anhydrides, which serve as both an acyl cation equivalent and a hydride source.
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