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  • Title: Haenamindole, an unusual diketopiperazine derivative from a marine-derived Penicillium sp. KCB12F005.
    Author: Kim JW, Ko SK, Son S, Shin KS, Ryoo IJ, Hong YS, Oh H, Hwang BY, Hirota H, Takahashi S, Kim BY, Osada H, Jang JH, Ahn JS.
    Journal: Bioorg Med Chem Lett; 2015 Nov 15; 25(22):5398-401. PubMed ID: 26403931.
    Abstract:
    During the chemical investigation of marine-derived fungus, an unusual diketopiperazine (DKP) alkaloid, haenamindole (1), was isolated from a culture of the marine-derived fungus Penicillium sp. KCB12F005. The structure of 1, which possesses benzyl-hydroxypiperazindione and phenyl-pyrimidoindole rings system in the molecule, was elucidated by analysis of NMR and MS data. The stereochemistry of 1 was determined by ROESY and advanced Marfey's method.
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