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Title: From Dispersed Microspheres to Interconnected Nanospheres: Carbon-Sandwiched Monolayered MoS2 as High-Performance Anode of Li-Ion Batteries. Author: Shao J, Qu Q, Wan Z, Gao T, Zuo Z, Zheng H. Journal: ACS Appl Mater Interfaces; 2015 Oct 21; 7(41):22927-34. PubMed ID: 26426361. Abstract: Hierarchical structured carbon@MoS2 (C@MoS2) microspheres and nanospheres composed of carbon-sandwiched monolayered MoS2 building blocks are synthesized through a facile one-pot polyvinylpyrrolidone (PVP) micelle-assisted hydrothermal route. The dimension and carbon content of C@MoS2 spheres are effectively controlled by singly adjusting the concentration of PVP, which plays the dual functions of soft-template and carbon source. As the anode materials of Li-ion batteries, C@MoS2 nanospheres present considerably higher capacity, better rate behavior and cycling stability than C@MoS2 microspheres. The reasons are attributed to the unique interconnected nanospherical morphology and the internal hierarchical construction of C@MoS2 nanospheres with expanded MoS2/carbon interlayer spacing.[Abstract] [Full Text] [Related] [New Search]