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  • Title: Reactivity differences of Sc3N@C(2n) (2n = 68 and 80). Synthesis of the first methanofullerene derivatives of Sc3N@D(5h)-C80.
    Author: Cerón MR, Izquierdo M, Alegret N, Valdez JA, Rodríguez-Fortea A, Olmstead MM, Balch AL, Poblet JM, Echegoyen L.
    Journal: Chem Commun (Camb); 2016 Jan 04; 52(1):64-7. PubMed ID: 26437751.
    Abstract:
    Using a purification method introduced earlier based on redox properties it was possible to isolate Sc3N@I(h)-C80 and Sc3N@D(3h)-C78 and a mixture of Sc3N@D(5h)-C80 and Sc3N@D3-C68. Taking advantage of their chemical reactivity differences, Sc3N@D(5h)-C80 was isolated from Sc3N@D3-C68 followed by further functionalization, giving rise to five new methano-derivatives of Sc3N@D(5h)-C80.
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