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  • Title: Visible-Light-Induced Decarboxylative Functionalization of Carboxylic Acids and Their Derivatives.
    Author: Xuan J, Zhang ZG, Xiao WJ.
    Journal: Angew Chem Int Ed Engl; 2015 Dec 21; 54(52):15632-41. PubMed ID: 26509837.
    Abstract:
    Visible-light-induced radical decarboxylative functionalization of carboxylic acids and their derivatives has recently received considerable attention as a novel and efficient method to create CC and CX bonds. Generally, this visible-light-promoted decarboxylation process can smoothly occur under mild reaction conditions with a broad range of substrates and an excellent functional-group tolerance. The radical species formed from the decarboxylation step can participate in not only single photocatalytic transformations, but also dual-catalytic cross-coupling reactions by combining photoredox catalysis with other catalytic processes. Recent advances in this research area are discussed herein.
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