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  • Title: Tunable porosity of 3D-networks with germanium nodes.
    Author: Monnereau L, Muller T, Lang M, Bräse S.
    Journal: Chem Commun (Camb); 2016 Jan 11; 52(3):571-4. PubMed ID: 26549732.
    Abstract:
    Eight hyper cross-linked polymers based on tetrakis(4-ethynylphenyl)germanium and tetrakis(4-ethynylphenyl)methane are presented. After investigation of their N2 adsorption properties at 77 K, the porosity of the germanium-based porous organic polymers (POPs) was modulated under acidic conditions, offering an easy and direct way, in a single step, to tune the adsorption properties.
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