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  • Title: Potential applications of cold sprayed Cu50Ti20Ni30 metallic glassy alloy powders for antibacterial protective coating in medical and food sectors.
    Author: El-Eskandrany MS, Al-Azmi A.
    Journal: J Mech Behav Biomed Mater; 2016 Mar; 56():183-194. PubMed ID: 26703232.
    Abstract:
    Mechanical alloying was utilized for synthesizing of metallic glassy Cu50Ti20Ni30 alloy powders, using a low energy ball milling technique. The metallic glassy powders obtained after 100 h of ball milling had an average particle size of 1.7 mm in diameter and possessed excellent thermal stability, indexed by a relatively high glass transition temperature (358.3 °C) with a wide supercooled liquid region (61 °C). This amorphous phase crystallized into Ti2Cu and CuTiNi2 ordered phases through two overlapped crystallization temperatures at 419.3 °C and 447.5 °C, respectively. The total enthalpy change of crystallization was -4.8 kJ/mol. The glassy powders were employed as feedstock materials to double-face coating the surface of SUS 304 substrate, using cold spraying process under helium gas pressure at 400 °C. This coating material had an extraordinary high nanohardness value of 3.1 GPa. Moreover, it showed a high resistance to wear with a low value of the coefficient of friction ranging from 0.45 to 0.45. Biofilms were grown on 20-mm(2) SUS304 sheets coated coupons inoculated with 1.5 × 10(8) CFU ml(-1)E. coli. Significant biofilm inhibition (p The inhibition of biofilm formation by nanocrystalline powders of Cu-based provides a practical approach to achieve the inhibition of biofilms formation.
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