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Title: Preparation of Poly(ionic liquid) Hollow Particles with Switchable Permeability. Author: Nakamura R, Tokuda M, Suzuki T, Minami H. Journal: Langmuir; 2016 Mar 15; 32(10):2331-7. PubMed ID: 26908213. Abstract: Poly(ionic liquid) (PIL) particles with a single-hollow structure are prepared by suspension polymerization from monomer droplets consisting of the hydrophobic ionic liquid monomer [2-(methacryloyloxy)ethyl]trimethylammonium bis(trifluoromethanesulfonyl)amide, ethylene glycol dimethacrylate, and n-butyl acetate containing dissolved poly(n-butyl methacrylate). The obtained PIL hollow particles' shells can be changed from hydrophobic to hydrophilic by anion exchange using a LiBr/ethanol solution. In the case of hydrophilic PIL hollow particles, the water-soluble fluorescent materials can penetrate into the hollow structure, whereas in the case of hydrophobic PIL hollow particles, penetration of the fluorescent materials is restricted. In addition, the encapsulated water-soluble materials can be preserved into the hollow part by changing the shell property of the PIL particle encapsulated with the water-soluble materials from hydrophilic to hydrophobic.[Abstract] [Full Text] [Related] [New Search]