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  • Title: Metal-metal chalcogenide molecular precursors to binary, ternary, and quaternary metal chalcogenide thin films for electronic devices.
    Author: Zhang R, Cho S, Lim DG, Hu X, Stach EA, Handwerker CA, Agrawal R.
    Journal: Chem Commun (Camb); 2016 Apr 11; 52(28):5007-10. PubMed ID: 26981781.
    Abstract:
    Bulk metals and metal chalcogenides are found to dissolve in primary amine-dithiol solvent mixtures at ambient conditions. Thin-films of CuS, SnS, ZnS, Cu2Sn(S(x),Se(1-x))3, and Cu2ZnSn(S(x)Se(1-x))4 (0 ≤ x ≤ 1) were deposited using the as-dissolved solutions. Cu2ZnSn(S(x)Se(1-x))4 solar cells with efficiencies of 6.84% and 7.02% under AM1.5 illumination were fabricated from two example solution precursors, respectively.
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